I Doubt It
Other than whatever you can find with Transat or Skyservice ( and I guess this winter WestJet), the AC flights they said were going to POP don't seem to have materialized in their on line or PDF schedules . Even then that was Toronto not Vancouver. Given the distance I doubt you will se that route anyway, even with the charters.
Otherwise American to Miami or JFK then to Vancouver (via either Toronto then AC or some other MIA- YVR route). Since there is a JFK to YVR non stop that would be the best bet. I think POP to JFK may need a drive to Santo Domingo first. Or Santiago to JFK - check AA.com
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