smr08,
You'd like to visit Acropolis Center and Bella Vista Mall. There I am sure you'll find most of what you are looking for. There are other stores spread through out town that carry Ralph Lauren, Hugo Boss, Faconable etc.
For water, local brands like Cristal are perfectly fine but if you prefer, they also sell evian, Dasani(coca-cola) etc., in most gas stations and supermarkets in Santo Domingo.
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