Ok, I see the confusion now. I was thinking you could switch also to the POP airport, but apparently that isn't an option.
If you change to the Breezes in POP, you can get there from SD by taking a taxi to Caribe Tours, a Caribe Tours bus to Sosua (RD$200), and a taxi to the breezes. This would take at least 5 hours. You would have no trouble getting to Breezes in POP the same day because buses leave hourly until about 6:30pm.
I'll let somebody with more knowledge than I have tell you how to get to Punta Cana. Then you can make your decision.
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