Hi Lori,
Greetings from Nova Scotia.
Air Canada flies that route...
AC1845 PUJ YYZ Saturdays Dep 18:00 Arr 22:30
AC1846 YYZ PUJ Saturdays Dep 07:00 Arr 11:25
BUT...
If your friend is Dominican the whole Visa thing could be a huge problem and the flight is very expensive (IMHO).
Good luck, you may need it.
Gregg
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