Express, air conditioned buses (with individual seats) from Santiago to Mao leave every 30 minutes from near the center of Santiago - the corner of Salvatore Cucurullo and Trienta de Marzo. It is the same address as 3 convenient, cheap, hotels - Colonial, Monterey, and Dorado.
It is the best way to get to Esperanza. The buses are far more frequent than Caribe Tours (or Espinal), and the station is nearer to the airport.
The fare from the airport to there should be whatever the fare is to downtown - probably about 100 pesos.
The bus fare to Esperanza or Mao was 30 pesos the last time I knew (about a year ago), but is probably 50 pesos now. The trip takes about 45 minutes.
There's also local (slow) buses leaving from the same place, but they take about 2 hours for the trip.
There is a 2nd rotunda, farther from the center, with buses to Mao and other places, near the Caribe Tours and Espinal stations.
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