Consider driving into Santo Domingo. Seeing the sights of the Colonial City and then taking the 4pm bus to Punta Cana. You can call a taxi company and for RD$150 the taxi will take you from the Colonial City to the Expresos Bavaro station at Calle Juan Sanchez Ramirez, perpendicular from the Supermercado Nacional. The taxi into Santo Domingo is about US$30, and then the bus out to Punta Cana is less than US$10 each. You would need to take a US$30 taxi to get to your final destination once you arrive in Punta Cana. Get off at the Veron bus station, that puts you closest to Catalonia. Adds up to around US$80. Doable, but would keep you on the go. The taxi option at US$125 would be zero stress, but then you don't get to see Santo Domingo, which is really worth it now that you are landing in Santo Domingo.
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