Driving at night is not advisable, especially for someone not familiar with driving in the DR, because of the drunks, bright lights that aren't dimmed, and animals and people on the road.
But it is staying light later with the approach of summer, so you should have daylight or twilight for most of the trip--proving you leave as close to 4 as possible. If you are held up, then you should think about getting a room in Sosua for the night and leave early in the morning. Or, as an alternative, you can take a taxi to Samana and rent a car there when you need one.
If you drive, hard to get lost since there is only one road. Get on the highway from the airport and stay on the same road into Nagua. There, you will come to a corner where you must turn left to go to Samana or right to go to San Francisco de Macoris. Turn left and stay on that road into Samana.
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