Or, you could fly charter. Ask at the STI airport.
There is no way you will make that flight using public transport on your flight day.
You could, however, go to Sto Dgo the day before, have some fun, get a good night's rest and be off in the morning from Parque Enriquillo ( I do believe) and be there in plenty of time for your flight.
Cost will be truly minimal, and including one of the smaller hotels talked about on this site, will be less than a taxi from Santo Domingo to Punta Cana...
All depends on what is holding you in Santiago....and on your pocketbook...
HB
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