What is your origin airport and airline service are you using? This lay over in Santo Domingo seems very unusual. Are you using a charter airline vis a scheduled airline? Are you coming from Europe? Knowing this information some of the forum users may be able to help you attain your goal
Please note American Airlines ( A partner with British Air) has flights direct to PUJ from MIA. If they do not have a direct flight for your schedule they can connect you from Miami to Punta Cana via San Juan, Puerto Rico.
Going to Santiago is not a recommended route for transit to Punta Cana, that if you desire to use land based transportation from there you will travel to Santo Domingo and then onward to Punta Cana, a duration of about 6-8 hours.
Good luck,
Regards,
PJT
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